Unless you also have a Samsung LA46A850 that would never work. Start again with a clean custom xorg.conf:
cp /etc/X11/xorg-nvidia.conf /storage/.config/xorg.conf
Add the following line to the "Device" section:
Option "ModeDebug" "True"
Reboot, SSH in and paste the content of /var/log/Xorg.0.0.log. Then overwrite /storage/.config/xorg.conf with my file and you're ready to start editing. Now you need to work you way through the Xorg.0.0.log data to find *your* Horizontal and Vertical refresh information and create "Modeline" entries for each mode you want Xorg to make available to XBMC.
e.g. you'll find horizontal / vertical info on lines like these:
[4078643.719] (--) NVIDIA(0): Valid HSync Range : 26.0 kHz - 68.0 kHz
[4078643.719] (--) NVIDIA(0): Valid VRefresh Range : 23 Hz - 60 Hz
Which become:
HorizSync 26-68
VertRefresh 23-60
Then you can look for the modepool information. This will look like:
[
4078643.858] (II) NVIDIA(0): --- Modes in ModePool for SAMSUNG (DFP-1) ---
[4078643.858] (II) NVIDIA(0): "nvidia-auto-select" : 1280 x 720 @ 60.0 Hz (from: EDID)
[4078643.858] (II) NVIDIA(0): "1920x1080" : 1920 x 1080 @ 59.94/60 Hz (CEA-861B Format 16) (from: EDID)
[4078643.858] (II) NVIDIA(0): "1920x1080_60" : 1920 x 1080 @ 59.94/60 Hz (CEA-861B Format 16) (from: EDID)
[4078643.858] (II) NVIDIA(0): "1920x1080_50" : 1920 x 1080 @ 50 Hz (CEA-861B Format 31) (from: EDID)
[4078643.858] (II) NVIDIA(0): "1920x1080_30" : 1920 x 1080 @ 29.97/30 Hz (CEA-861B Format 34) (from: EDID)
[4078643.858] (II) NVIDIA(0): "1920x1080_25" : 1920 x 1080 @ 25 Hz (CEA-861B Format 33) (from: EDID)
[4078643.858] (II) NVIDIA(0): "1920x1080_24" : 1920 x 1080 @ 23.97/24 Hz (CEA-861B Format 32) (from: EDID)
[4078643.858] (II) NVIDIA(0): "1920x1080_60i" : 1920 x 1080 @ 60.1 Hz Interlace (from: EDID)
[4078643.858] (II) NVIDIA(0): "1920x1080_60i_0" : 1920 x 1080 @ 59.94/60 Hz (CEA-861B Format 5) (from: EDID)
[4078643.858] (II) NVIDIA(0): "1920x1080_50i" : 1920 x 1080 @ 50.0 Hz Interlace (from: EDID)
[4078643.858] (II) NVIDIA(0): "1280x720" : 1280 x 720 @ 60.0 Hz (from: EDID)
[4078643.858] (II) NVIDIA(0): "1280x720_60" : 1280 x 720 @ 60.0 Hz (from: EDID)
[4078643.858] (II) NVIDIA(0): "1280x720_60_0" : 1280 x 720 @ 59.94/60 Hz (CEA-861B Format 4) (from: EDID)
[4078643.858] (II) NVIDIA(0): "1280x720_50" : 1280 x 720 @ 50.0 Hz (from: EDID)
[4078643.858] (II) NVIDIA(0): "720x576" : 720 x 576 @ 50.0 Hz (from: EDID)
[4078643.858] (II) NVIDIA(0): "720x576_50" : 720 x 576 @ 50.0 Hz (from: EDID)
[4078643.858] (II) NVIDIA(0): "720x480" : 720 x 480 @ 59.9 Hz (from: EDID)
[4078643.858] (II) NVIDIA(0): "720x480_60" : 720 x 480 @ 59.9 Hz (from: EDID)
[4078643.859] (II) NVIDIA(0): "640x480" : 640 x 480 @ 60.0 Hz (from: EDID)
[4078643.859] (II) NVIDIA(0): "640x480_60" : 640 x 480 @ 60.0 Hz (from: EDID)
[4078643.859] (II) NVIDIA(0): --- End of ModePool for SAMSUNG (DFP-1): ---
This tells you what modes are supported. the ones you're interested in are the 1920x1080 resolutions, typically 60/50/302/25/24 Hz. e.g.
[4078643.858] (II) NVIDIA(0): "1920x1080_60" : 1920 x 1080 @ 59.94/60 Hz (CEA-861B Format 16) (from: EDID)
[4078643.858] (II) NVIDIA(0): "1920x1080_50" : 1920 x 1080 @ 50 Hz (CEA-861B Format 31) (from: EDID)
[4078643.858] (II) NVIDIA(0): "1920x1080_30" : 1920 x 1080 @ 29.97/30 Hz (CEA-861B Format 34) (from: EDID)
[4078643.858] (II) NVIDIA(0): "1920x1080_25" : 1920 x 1080 @ 25 Hz (CEA-861B Format 33) (from: EDID)
[4078643.858] (II) NVIDIA(0): "1920x1080_24" : 1920 x 1080 @ 23.97/24 Hz (CEA-861B Format 32) (from: EDID)
Now you have the long and boring task to finding those modes within the file and rearranging the data to create your modelines. As an example, the 60Hz mode will look something like this:
[4078643.720] (--) NVIDIA(0): 1920 x 1080 @ 60 Hz
[4078643.720] (--) NVIDIA(0): Pixel Clock : 74.25 MHz
[4078643.720] (--) NVIDIA(0): HRes, HSyncStart : 1920, 2008
[4078643.720] (--) NVIDIA(0): HSyncEnd, HTotal : 2052, 2200
[4078643.720] (--) NVIDIA(0): VRes, VSyncStart : 1080, 1084
[4078643.720] (--) NVIDIA(0): VSyncEnd, VTotal : 1094, 1124
[4078643.720] (--) NVIDIA(0): H/V Polarity : +/+
Which you flatten into a single line that looks like this:
Modeline "1920x1080_60" 74.25 1920 2008 2052 2200 1080 1084 1094 1124 +HSync +Vsync
Rinse and repeat for each mode, then edit my "Modes" line in the screen section so it looks like:
Modes "1920x1080_60" "1920x1080_50" "1920x1080_30" "1920x1080_25" "1920x1080_24"
Once you're done, reboot and in theory you should be all configured with static modelines. You may not get it all correct the first time as the log un-helpfully contains way too much data. Work on adding a single 60Hz mode first, then add 50, etc. until you're done. The process is never quick and there are no shortcuts.